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[Configuration]
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Onlyonce=-1
In the settings of the second one on the Behavior page, ◉ An alternative file manager is selected.
In the field below it's set: "C:\Portable\Total Commander\TOTALCMD.EXE " /O /S/L=%DriveLetter%
After calling Browse Drive from the menu of the selected drive, a new instance of TC with the specified parameters is opened.